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In this Tuesday, Nov. 19, 2013, file photo, George Zimmerman listens in court, in Sanford, Fla., during his hearing on charges including aggravated assault stemming from a fight with his girlfriend. The Seminole County Sheriff's Office says Zimmerman was arrested in Lake Mary, Friday, Jan. 9, 2015 on an aggravated assault charge, and is being held at the John E. Polk Correctional Facility. (AP Photo/Orlando Sentinel, Joe Burbank, Pool, File)

ORLANDO - George Zimmerman became angry and threw a wine bottle at his ex-girlfriend when she tried to break up with him, according to a police report released Monday.

Zimmerman denied throwing the bottle and disputed her claim that he destroyed her cell phone last week, according to the report, which chronicles his latest run-in with police since he was acquitted of murdering Trayvon Martin in 2013. The killing of the unarmed black teen touched off protests across the country.

Instead, Zimmerman said, he was only trying to prevent her from entering his home.

The former neighborhood watch volunteer was arrested Friday in Lake Mary and charged with aggravated assault. He was released Saturday on $5,000 bond.

Zimmerman didn't respond to a message left on his cell phone Monday by The Associated Press.

Officers patrolling the neighborhood where Zimmerman lives last week heard the sound of glass shattering, and then saw the former girlfriend drive out of the driveway. They pulled her over for a traffic stop a few streets over because she didn't have her lights on.

She explained that Zimmerman became angry after she told him she didn't want to take the relationship further, and they also argued over a painting she had that he wanted returned. Zimmerman made threats and threw the wine bottle, which didn't hit her, she said.

Detectives described her as "extremely emotional, crying, mad and upset" and said she became reluctant to cooperate when she realized that officers might be conducting an investigation. She called her former boyfriend "that psycho, George Zimmerman" and said several times that she should have known better than to get involved with him.

The ex-girlfriend, whose name is redacted, told investigators that she had had an "intimate relationship" with Zimmerman since the end of last year.

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Zimmerman denies throwing bottle at girlfriend